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Macromolecular Chemistry II – Prof. Dr. Andreas Greiner (Macromolecular Chemistry & Technology) & Prof. Dr. Seema Agarwal (Advanced Sustainable Polymers)

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Synthesis and degradation study of graft copolymers of poly(limonene carbonate)

22.09.2023

Dipannita Ghosh and Seema Agarwal

Polymer Chemistry, 2023. https://doi.org/10.1039/D3PY00932G

Synthesis and degradation study of graft copolymers

The utility of poly(limonene carbonate) (PLimC) for real-world application as an environmentally friendly polymer can be enhanced by improving its brittleness and degradation. In this work, a chemical approach for making graft polymer architecture has been presented for property modification. Grafted polyesters onto PLimC with microphase separation and enhanced hydrophilicity were synthesized and characterized in depth for their structural, thermal, mechanical and morphological properties. The effect of structure on enzymatic and wastewater degradation, assessed by monitoring the production of CO2 and the mechanism of degradation, is studied by a combination of different analytical methods.

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